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The Capital Late Show with Marvin Humes 10pm - 1am
5 October 2012, 16:30 | Updated: 5 October 2012, 16:46
The 'Someone Like You' singer's Bond theme and Rihanna's new release are in the running for number one this weekend.
Adele's newly released James Bond theme 'Skyfall' and Rihanna's latest single 'Diamonds' will both challenge One Direction on the Vodafone Big Top 40 this weekend.
The 'What Makes You Beautiful' singers ended PSY's reign at the top of the chart last Sunday (30th September) with their brand new single 'Live While We're Young', the first release from their new album 'Take Me Home'.
Adele unveiled her theme song for the Sam Mendes directed James Bond film Skyfall earlier today (5th October) at exactly 0:07 GMT, and the single was released straight afterwards, making the 'Rolling In The Deep' star a challenger for this weekend's chart show.
Rihanna is also still in the running with her single 'Diamonds', released last week, which is the first track to be lifted from her upcoming seventh studio album.
Check out a picture of One Direction's single artwork for 'Live While We're Young' below:
Conor Maynard and Ne-Yo's team-up track 'Turn Around' is also out, and Conor will be on hand on the Big Top 40 to find out where he charts, while Swedish House Mafia release their latest track 'Don't You Worry Child'.
Join Rich and Kat on the Vodafone Big Top 40 this Sunday (7th October) from 4pm to find out this weekend's number one single.