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29 February 2012, 12:29 | Updated: 29 February 2012, 12:35
The 'We Found Love' star is due to be interviewed on the ITV show.
Rihanna has hinted that she may perform new single 'Talk That Talk' when she appears on The Jonathan Ross Show this weekend.
The singer is expected to be interviewed as well as perform on the ITV1 show on Saturday (3rd March).
In a message on Twitter, RiRi said: "Jonathan Ross rehearsal .... Talk that talk to me yeah!!!"
RiRi will be joined by fellow guests Lionel Richie, Imelda Staunton and Michael Ball on this week's episode.
Rihanna is currently in the UK as part of an extended promotional trip, which included her performance at the BRIT Awards earlier this month.
Earlier this week, the 'We Found Love' star was mobbed by fans as she left her hotel in London.