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8 October 2012, 10:24 | Updated: 8 October 2012, 15:26
The 'Rolling In The Deep' star's Vodafone Big Top 40 number one soundtracks the Daniel Craig promo.
Adele's song 'Skyfall', taken from the new James Bond film of the same name, features in the latest trailer for the movie.
The 'Someone Like You' star only recently confirmed her involvement with the track following months of speculation.
She posted an image on her Twitter account showing the booth set for the track before premiering the song on her official site last week at 0.07 hrs.
Tubes on the underground crashing, an array of Union Jack draped coffins and a steamy shower sequence all feature in the explosive new trailer for the movie.
The track has since knocked One Direction off the top of the Vodafone Big Top 40 this week, just days after it was made available to download.
Speaking about her decision to pen the song, Adele called it a "no brainer".
She said: "I'll be backcombing my hair when I'm 60 telling people I was a Bond girl back in the day I'm sure!"
You can watch the new trailer to the James Bond movie 'Skyfall' below:
Skyfall will hit cinema screens at the end of the month on 26th October.