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28 November 2013, 07:51 | Updated: 7 January 2014, 11:35
James Corden will also once again be taking over hosting duties with Arctic Monkeys also confirmed to perform.
Katy Perry and Arctic Monkeys are the first confirmed performers for the BRIT Awards 2014.
The 'I Kissed A Girl' singer will take to the stage at London's O2 Arena for one of the biggest nights of the music calendar on 19th February.
"The Brits has always showcased the music that I love and am influenced by," the US star said about her appearance. "It's an honour to play at such a prestigious event where musicality shines at its brightest."
The show will once again see comedian and actor James Corden hosting – his fifth and final time taking the reigns.
Chairman of the BRIT Awards, Christian Tattersfield added that they have been "extremely ambitious" for next year's show with the aims to showcase "global superstars" and celebrate the "incredible success of British music."
"We are going to pull out all the stops to make this the biggest and most exciting Brits ever," he declared.
Tickets for the BRIT Awards 2014 go on sale from 10am today (28th November).
Keep it Capital for the first news of the full line-up for next year's BRITs and the nominations list.
Katy will be at London's O2 Arena next month for Capital's Jingle Bell Ball 2013.