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Capital Breakfast with Roman Kemp 6am - 10am
1 February 2012, 14:23 | Updated: 1 February 2012, 14:35
The Black Eyed Peas star will be aiming to stop David Guetta from claiming a second week at the top.
Will.i.am will be looking to stop David Guetta from achieving a second week at the top of the Vodafone Big Top 40 chart this weekend with his new single 'T.H.E (The Hardest Ever)'.
The French DJ claimed the top spot last Sunday with his Sia collaboration 'Titanium' which put an end to Jessie J's reign at the summit.
Madonna, who will be performing at this weekend's Super Bowl may also be celebrating a chart success when her Nicki Minaj and M.I.A featuring track 'Give me All Your Luvin' is released this week.
Canadian newcomer Alyssa Reid may also be set to make a surge for the top of the chart with her single 'Alone Again.'
Meanwhile, Will.i.am ecently told Capital FM that he has recorded a classical song with former Pussycat Doll Nicole Scherzinger as well as teaming up with Alicia Keys and Britney Spears on new album '#willpower'.
The Vodafone Big Top 40 with Rich and Kat airs every Sunday from 4-7pm.