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20 March 2012, 19:03 | Updated: 20 March 2012, 19:49
The 'Earthquake' singer is due to perform on the ITV1 show this weekend ahead of his album launch.
Labrinth has confirmed he will be the musical guest on this week's Jonathan Ross Show.
The 'Last Time' singer will join host Jonathan Ross on the ITV1 show on Saturday (24th March), alongside main guest Simon Cowell.
"I'm here right now sitting next to Danny Devito and simoncowell," Labrinth tweeted earlier this evening (20th March).
Labrinth featured in an exclusive CapitalFM.com session earlier today during which he performed acoustic versions of all his hits to date including 'Let The Sun Shine', 'Last Time' and his cover of 'Express Yourself'.
The 'Earthquake' rapper is preparing to launch his debut solo album 'Electronic Earth' on 2nd April.