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The 'Changed The Way You Kiss Me' star will be joined by DJ Fresh and Hadouken at the gig in September.
Example has become the latest named added to the line-up for the iTunes Festival 2012.
The 'Stay Awake' star will be joined by DJ Fresh and Hadouken on Monday 17th September when he takes to the stage at the Roundhouse in Camden, London.
The rapper joins a bill which includes opening act Usher, Labrinth, One Direction and Jessie J.
Calvin Harris was recently added the line-up in an event which takes place every night throughout September.
It will be the third appearance in a row for Example who headlined in 2011 and was a special guest of N-Dubz the year before.
The star is set to release his new album later in the year and recently premiered new single 'Say Nothing' for the first time on Capital.
Other big name acts also set to take to perform at the iTunes Festival 2012 include Ed Sheeran, Olly Murs and JLS.
Meanwhile, Example was among the stars who took to his Twitter account this weekend to praise the London 2012 Olympics triumph of 100m gold medalist and fastest man on the planet, Usain Bolt.