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26 September 2012, 11:47 | Updated: 26 September 2012, 12:13
The 'Sexy Back' singer was taking part in the sporting day ahead of the USA vs Europe golf tournament this weekend.
Justin Timberlake joined celebrity stars such as Bill Murray and Olympic swimming champion Michael Phelps for a celebrity golf tournament in Chicago yesterday (25th September), ahead of this weekend's Ryder Cup 2012.
The 'Cry Me A River' star partnered the Ghostbusters actor for the day, playing against a professional team made up of Dick Stockton and Tom Lehman.
The singer turned actor's fiancé Jessica Biel was also pictured walking the fairways at the Medinah Country Club in Illinois as she held onto a parasol to shield herself from the glorious sunshine.
The Total Recall star looked in high sprits throughout as she enjoyed the Celebrity Scramble event, which was eventually won by the partnership of George Lopez and Michal Phelps.
You can view a picture of Jessica Biel cheering on Justin Timberlake and Bill Murray below:
Justin will be acting as a team ambassador for the USA squad as they face off against the best golfers from Europe in the three-day event, which takes place on Friday.
"It's going to be a special week for golf fans around the world, me the most," he said at the announcement earlier this summer.
You can check out a picture of Justin after hitting a drive down the fairway at the tournament in Chicago below:
Meanwhile, Justin and Jessica are rumoured to be getting married next month following recent reports they had tied the knot in secret at a ski resort last month.
Justin also helped launch the new version of social site Myspace yesterday and has been pictured on his stag do this past week.