The artists will also be joined by the likes of Rizzle Kicks, Jamie Cullum and Tinie Tempah for the gig in London this September.
Emeli Sande Confirms She Will Be Performing At BRIT Awards 2013 – Audio
The 'Read All About It' star speaks to Capital on the red carpet of the nomination's ceremony.
Emeli Sande has confirmed that she will perform at this year's BRIT Awards.
The 'Next To Me' singer spoke to Capital FM on the red carpet of the nominations ceremony about being shortlisted for four awards and her plans for her performance on the night.
The singer admitted to being incredibly "excited" for the big night, and said she would love to take to the stage with Labrinth following the success of their collaboration 'Beneath Your Beautiful'.
"That would be a good idea. I'm going to look into it," she said. "There's so many people I'd love to meet and collaborate with so we'll see. I'm going to get my thinking cap on."
The singer has received nods in the Best Album, Best Female and Best British Single with Capital FM categories.
Last year saw Emeli take home the Critics' Choice Award, which she is set to be presented to Tom Odell later this evening.
Listen to Emeli Sande speaking to Capital FM about her plans for performing at the BRIT Awards 2013.
The BRIT Awards 2013 will take place live from London's O2 Arena on 20th February.
Latest Emeli Sande
The 'Next To Me' singer has been honoured for her work in music after attending Glasgow University back in 2009.
The 'Next To Me' singer recorded the song for the soundtrack to the new movie The Great Gatsby.
The 'Next To Me' singer is interrogated in the music video for her new solo single.